Fluctuation theorem and Onsager reciprocity relations.
نویسندگان
چکیده
The Onsager and higher-order reciprocity relations are derived from a fluctuation theorem for nonequilibrium reactions ruled by the chemical master equation. The fluctuation theorem is obtained for the generating function of the macroscopic fluxes between chemiostats maintaining the system in a nonequilibrium steady state. The macroscopic affinities associated with the fluxes are identified by graph theory. The Yamamoto-Zwanzig formulas for the reaction constants are also derived from the fluctuation theorem.
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عنوان ژورنال:
- The Journal of chemical physics
دوره 121 13 شماره
صفحات -
تاریخ انتشار 2004